The orthogonal decomposition of the Webster curvature provides us a way to characterize some canonical metrics on a pseudo-Hermitian manifold. We derive some subelliptic differential inequalities from the Weitzenb\"ock formulas for  the traceless pseudo-Hermitian Ricci tensor of Sasakian manifolds with constant pseudo-Hermitian scalar curvature and the Chern-Moser tensor of  the Sasakian pseudo-Einstein manifolds respectively. By means of either subelliptic estimates or maximum principle, some rigidity theorems are established to characterize Sasakian pseudo-Einstein manifolds among Sasakian manifolds with constant pseudo-Hermitian scalar curvature and Sasakian space forms among Sasakian pseudo-Einstein manifolds respectively. 

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